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Preparation of Polysulfone Membranes using Ionic Liquid [C16mim][SCN] as a pore-former and plasticizer  
Preparation of Polysulfone Membranes using Ionic Liquid [C16mim][SCN] as a pore-former and plasticizer
資料類型: PDF文件
關鍵詞: Ionic  liquid  synthesis  Polysulfone  membrane  Pore-forming  Preparation  
資料大?。?/td> 967K
所屬學科: 分子表征
來源: 2009高分子材料先進制造業(yè)(青島)國際論壇(8.19-8.21,青島)
簡介:
Polysulfone(PSf)membraneswerepreparedbythewet-phase-inversionusing1-hexadecyl-3-methylimidazoliumthiocyanate[C16mim][SCN]asannewadditive.Scanningelectronmicroscopewasutilizedtovisualizecross-sectionsofthemembranestogainmorebetterunderstandingtheinfluenceof[C16mim][SCN]onthepore-forming.Moreover,Membrane-formingmechanismusingionicliquidasaporeformerwasalsodiscussed.Theresultsshowedthationicliquid[C16mim][SCN]hadrestrainedthedemixingofthecastingsolutionsandhastheabilityofthepore-forming,higherthanthoseofitsanaloguesofPEG400.Withincreaseofconcentrationofionicliquid[C16mim][SCN]incastingsolutions,thestructuresofthemembraneschangedfromasymmetricfingerporestothespongy-finger-macrovoidstructureofthepores.ComparedwithPEG400asapore-former,[C16mim][SCN]hasthepore-formingabilitytothemembraneatlowerconcentrationof[C16mim][SCN]inthecastingsolution.Especially,atthe4:76ratioof[C16mim][SCN]/NMP,thepreparedmembranehastheasymmetricfinger-poresstructure,withthe2~6μmporesclosetosurfacelayerandthe10~24μmporeforitssublayer.ItsretentionrateofPEG10000andsolutionfluxare97.1%and48.7L·h-1·m-2.Meanwhile,ionicliquidcanbeaplasticizer,accordingthethermalpropertiesofthemembranes.
作者: ZHAO Yameia, HU Xiaolingb, YU Jinyangc Guan Ping
上傳時間: 2009-11-06 11:30:54
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